Publication

Interplay between conductivity, matrix relaxations and co,position of Ca-Polyoxyethylene polymer Electrolytes Autors: Gioele Pagot, Keti Vezzù, Cynthia Susana Martinez-Cisneros, Claire Antonelli, Belen Levenfeld, Alejandro Varez, Jean-Yves Sanchez and Vito Di Noto Summary: In this report, the conductivity mechanism of Ca2+-ion in polyoxyethylene (POE) solid polymer electrolytes (SPEs) for calcium secondary batteries is investigated by broadbandContinue reading “Publication”

Publication

Opening the door to liquid-free polymer electrolytes for calcium batteries Autors: C.S. Martinez Cisneros, A. Fernandez, C. Antonelli, A. Varez, K. Vezzù, V. Di Noto, J.-Y. Sanchez Summary: This work studies calcium-conducting, solvent-free polymer electrolytes in the framework of today’s post-lithium battery strategies. The samples consist of three calcium salts: (i) Ca(CF3SO3)2; (ii) Ca(TFSI)2; andContinue reading “Publication”

Publication

Cathode–Electrolyte Interphase in a LiTFSI/Tetraglyme Electrolyte Promoting the Cyclability of V2O5 Autors: Xu Liu, Maider Zarrabeitia, Bingsheng Qin, Giuseppe Antonio Elia and Stefano Passerini. Summary: The use of a LiTFSI/tetraglyme (1:1 in mole ratio) electrolyte yields a highly enhanced cycling ability of V2O5 (from 20% capacity retention to 80% after 100 cycles at 50 mAContinue reading “Publication”

Publication

Operando pH measurements decipher H+/Zn2+ Intercalation chemistry in high-performance aqueous Zn/δ-V2O5 Batteries Autors: Xu Liu, Holger Euchner, Maider Zarrabeitia, Xinpei Gao, Giuseppe Antonio Elia, Axel Groß and Stefano Passerini. Summary: Vanadium oxides have been recognized to be among the most promising positive electrode materials for aqueous zinc metal batteries (AZMBs).To shed light on the intercalationContinue reading “Publication”

Publication

Alkoxy-functionalized ionic liquid electrolytes: understanding ionic coordination of calcium ion speciation for the rational design of calcium electrolytes Autors: Xinpei Gao, Xu Liu, Alessandro Mariani, Giuseppe Antonio Elia,Manuel Lechner, Castern Streb, Stefano Passerini. Summary: In this work of Karlsruhe Institute of Technology (KIT), they report the design of alkoxy-functionalized cations to control Ca-ion speciation inContinue reading “Publication”